Search results for "thermal [correlation function]"
showing 10 items of 1923 documents
Thermoplastic Properties of Endodontic Gutta-percha: A Thermographic In Vitro Study
2014
Abstract Introduction Endodontic gutta-percha undergoes deformation at temperatures above 65°C. The temperature influence of heat carriers on gutta-percha cones was investigated in vitro. Methods Six single-rooted extracted teeth were embedded in resin and fixed. The root canals were prepared (ProFile; Dentsply Maillefer, Ballaiques, Switzerland) to different tapers and bisected. Thermographic images when heating the gutta-percha cones (Roeko, Langenau, Germany) with a heat carrier (ML .12; SybronEndo, Orange, CA) at 1 and 5 mm from the working length were made with an infrared thermal imaging camera (ThermaCam P640; Flir Systems, Taby, Sweden). The device temperature was preset at 200°C. T…
Extremely rapid acclimation of Escherichia coli to high temperature over a few generations of a fed-batch culture during slow warming
2014
This study aimed to demonstrate that adequate slow heating rate allows two strains of Escherichia coli rapid acclimation to higher temperature than upper growth and survival limits known to be strain-dependent. A laboratory (K12-TG1) and an environmental (DPD3084) strain of E. coli were subjected to rapid (few seconds) or slow warming (1 degrees C 12 h(-1)) in order to (re) evaluate upper survival and growth limits. The slow warming was applied from the ancestral temperature 37 degrees C to total cell death 46-54 degrees C: about 30 generations were propagated. Upper survival and growth limits for rapid warming (46 degrees C) were lower than for slow warming (46-54 degrees C). The thermal l…
Thermal lens spectrometry in biochemical analysis.
1994
The photothermal spectroscopic techniques, with special emphasis on the thermal lens spectrometry (TLS), are introduced to the non-specialist in laser spectroscopy. The following topics are treated on an elementary basis: fundamentals and analytical characteristics, instrumentation, selectivity and multi-wavelength capability, the models describing the signal-concentration relationship, the sensitivity, background noise and limits of detection, the influence of light scattering and flow. Applications related to the fields of clinical and biochemical analysis and organic pollution are given. The thermal lens circular dichroism and the infrared TLS are also briefly outlined.
Impulsive solvent heating probed by picosecond x-ray diffraction
2006
The time-resolved diffraction signal from a laser-excited solution has three principal components: the solute-only term, the solute-solvent cross term, and the solvent-only term. The last term is very sensitive to the thermodynamic state of the bulk solvent, which may change during a chemical reaction due to energy transfer from light-absorbing solute molecules to the surrounding solvent molecules and the following relaxation to equilibrium with the environment around the scattering volume. The volume expansion coefficient alpha for a liquid is typically approximately 1 x 10(-3) K(-1), which is about 1000 times greater than for a solid. Hence solvent scattering is a very sensitive on-line t…
A model for Ischia hydrothermal system: Evidences from the chemistry of thermal groundwaters.
2009
Abstract Ischia volcano, in Central Italy, has long been known for its copious surface hydrothermal manifestations, signs of a pervasive circulation of hot fluids in the subsurface. Because of the significant chemical heterogeneity of fumarolic gas discharges and hot spring discharges, evidences of a complex hydrothermal setting, a definite model of fluid circulation at depth is currently unavailable, in spite of the several previous efforts. Here, we report on the chemical and isotopic composition of 120 groundwater samples, collected during several sampling surveys from 2002 to 2007. The acquired data suggest that the composition of surface manifestations reflect contributions from meteor…
Analyses of phase change materials’ efficiency in warm-summer humid continental climate conditions
2017
The usage of phase change materials (PCMs) is a way to store excess energy pro- duced during the hot time of the day and release it during the night thereby reducing the overheating problem. While, in Latvian climate conditions overheating is not a big issue in traditional buildings since it happens only a couple of weeks per year air conditioners must still be installed to maintain thermal comfort. The need for cooling in recently built office buildings with large window area can increase signi cantly. It is therefore of great interest if the ther- mal comfort conditions can be maintained by PCMs alone or with reduced maximum power of installed cooling systems. Our initial studies show tha…
Experimental testing of phase change materials in a warm-summer humid continental climate
2019
Abstract The construction industry (and buildings) is one of the largest energy consuming and CO2 emitting sectors in the world. To counter this, more lightweight structures are being used and energy saving applications are being developed. Phase change materials (PCM) are materials that can be considered to tackle these new challenges. It has been proven that PCMs can be passively used to improve the thermal mass of lightweight structures, which improves thermal comfort and reduces peak cooling and heating loads and therefore provides energy savings. To use these materials in an active way, they should be used together with ventilation, cooling or heating equipment, and collectors to accum…
Experimental investigation on lithium borohydride hydrolysis
2010
Abstract Lithium borohydride, one of the highest energy density chemical energy carriers, is considered as an attractive potential hydrogen storage material due to its high gravimetric hydrogen density (19.6%). Belonging to borohydride compounds, it presents a real issue to overcome aims fixed by the U.S. Department of Energy in the field of energy, and so crystallizes currently attention and effort to use this material for large scale civil and military applications. However, due to its important hygroscopicity, lithium borohydride is a hazardous material which requires specific handling conditions for industrial aspects. In order to understand much more the reaction mechanism involved bet…
High resolution remote estimation of soil surface water content by a thermal inertia approach
2009
Summary The spatial distribution of soil surface water content in a bare soil was evaluated by a thermal inertia approach from high resolution visible/near infrared (VIS/NIR) and thermal infrared (TIR) airborne data. Given that the relationship between the thermal inertia and the soil water content strongly depends on the accurate estimation of the soil thermal conductivity, two different empirical models were applied to estimate it. Remotely estimated water contents were tested with time domain reflectometry (TDR) measurements collected on a 110 × 90 m 2 bare field in coincidence with airborne over-flights. The thermal conductivity model by Johansen (1975) produced more accurate estimates …
Quantification of deep CO2 fluxes from Central Italy. Examples of carbon balance for regional aquifers and of soil diffuse degassing.
1999
Abstract In Central Italy non-volcanic CO 2 is discharged by focused degassing (strong diffuse emission and vents) and by high-CO 2 groundwater. 3 He / 4 He data and the carbon isotopic composition of CO 2 are compatible with derivation from mantle degassing and/or metamorphic decarbonation. The gases produced at depth accumulate in permeable reservoirs composed of Mesozoic carbonates. When total pressure (roughly corresponding to p CO 2 ) of the reservoir fluid exceeds hydrostatic pressure, a free gas phase forms gas reservoirs within the permeable host rocks from which gases may escape toward the surface. This process generates both the focused vents and the CO 2 -rich springs which chara…